Sodium-Ion Cathode Materials — O3/P2 Layered Oxides, Prussian Blue Analogues, and NASICON Frameworks
Sodium-ion batteries have no single dominant cathode chemistry — unlike lithium-ion where NMC and LFP have converged as the two primary commercial choices. Three cathode families compete in Na-ion: layered transition metal oxides (high energy density, phase instability), Prussian Blue Analogues (cheap synthesis, moisture sensitivity), and NASICON-type frameworks (ultra-stable, lower energy density). Understanding the crystal structures, sodium storage mechanisms, and failure modes of each — and why the anode's hard carbon microstructure is the other half of the Na-ion cell performance equation — explains why CATL chose O3-type layered oxide for their first generation and why the choice may change in the second.